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Record Information |
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| Version |
1.0 |
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| Update Date |
1/22/2018 12:54:54 PM |
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Metabolite ID | PAMDB120113 |
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Identification |
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| Name: |
protochlorophyllide a |
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| Description: | A cyclic tetrapyrrole anion that is the conjugate base of protochlorophyllide, arising from deprotonation of the carboxy group. |
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Structure |
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| Synonyms: | - Monovinyl protochlorophyllide a
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Chemical Formula: |
C35H30N4O5MG |
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| Average Molecular Weight: |
610.951 |
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| Monoisotopic Molecular
Weight: |
612.2223 |
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| InChI Key: |
SSIKFLKOTZKJAG-UAVVDGTISA-K |
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| InChI: | InChI=1S/C35H33N4O5.Mg/c1-8-19-15(3)22-12-24-17(5)21(10-11-28(40)41)32(38-24)30-31(35(43)44-7)34(42)29-18(6)25(39-33(29)30)14-27-20(9-2)16(4)23(37-27)13-26(19)36-22;/h8,12-14H,1,9-11H2,2-7H3,(H3,36,37,38,39,40,41,42);/q-1;+2/p-3/b22-12-,23-13-,24-12-,25-14-,26-13-,27-14-,32-30-; |
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| CAS
number: |
14751-08-7 |
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| IUPAC Name: | {3- [(21R)-9-ethenyl-14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-3,4-didehydrophorbin-3-yl-κ2N23,N25]propanoato(3−)}magnesate(1−) |
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Traditional IUPAC Name: |
Not Available |
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| SMILES: | C=CC2(=C(C)C5(=CC1(C(C)=C(CCC(=O)[O-])C(N=1)=C7([C-](C(OC)=O)C(=O)C6(C(C)=C4(N([Mg]N(C2=CC3(C(C)=C(CC)C(N=3)=C4))5)C=67)))))) |
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Chemical Taxonomy |
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Taxonomy Description | This compound belongs to the class of organic compounds known as metallotetrapyrroles. These are polycyclic compounds containing a tetrapyrrole skeleton combined with a metal atom. |
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Kingdom |
Organic compounds |
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| Super Class | Organoheterocyclic compounds |
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Class |
Tetrapyrroles and derivatives |
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| Sub Class | Metallotetrapyrroles |
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Direct Parent |
Metallotetrapyrroles |
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| Alternative Parents |
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| Substituents |
- Metallotetrapyrrole skeleton
- Aryl ketone
- Dicarboxylic acid or derivatives
- Substituted pyrrole
- Pyrrole
- Methyl ester
- Heteroaromatic compound
- Vinylogous amide
- Carboxylic acid ester
- Ketimine
- Ketone
- Organic metal salt
- Azacycle
- Carboxylic acid
- Carboxylic acid derivative
- Metalloheterocycle
- Organonitrogen compound
- Organic oxygen compound
- Organic salt
- Carbonyl group
- Imine
- Organic nitrogen compound
- Organooxygen compound
- Organopnictogen compound
- Organic oxide
- Hydrocarbon derivative
- Organic anion
- Aromatic heteropolycyclic compound
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| Molecular Framework |
Aromatic heteropolycyclic compounds |
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| External Descriptors |
Not Available |
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Physical Properties |
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| State: |
Not Available |
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| Charge: | -1 |
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Melting point: |
Not Available |
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| Experimental Properties: |
| Property | Value | Reference |
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| Melting Point | Not Available | Not Available | | Boiling Point | Not Available | Not Available | | Water Solubility | Not Available | Not Available | | LogP | Not Available | Not Available |
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| Predicted Properties |
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Biological Properties |
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| Cellular Locations: |
Not Available |
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| Reactions: | |
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Pathways: |
- chlorophyllide a biosynthesis III (aerobic, light independent)PWY-7159
- chlorophyllide a biosynthesis I (aerobic, light-dependent)CHLOROPHYLL-SYN
- chlorophyllide a biosynthesis II (anaerobic)PWY-5531
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Spectra |
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| Spectra: |
Not Available |
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References |
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| References: |
- Meskauskiene R, Nater M, Goslings D, Kessler F, op den Camp R, Apel K: FLU: a negative regulator of chlorophyll biosynthesis in Arabidopsis thaliana. Proc Natl Acad Sci U S A. 2001 Oct 23;98(22):12826-31. Epub 2001 Oct 16. [11606728 ]
- Yannai, Shmuel. (2004) Dictionary of food compounds with CD-ROM: Additives, flavors, and ingredients. Boca Raton: Chapman & Hall/CRC.
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| Synthesis Reference: |
Not Available |
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| Material Safety Data Sheet (MSDS) |
Not Available |
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Links |
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| External Links: |
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