ethanesulfonate (PAMDB006371)
| Record Information | |||||||||||||||||||||||||||||
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| Version | 1.0 | ||||||||||||||||||||||||||||
| Update Date | 1/22/2018 12:54:54 PM | ||||||||||||||||||||||||||||
| Metabolite ID | PAMDB006371 | ||||||||||||||||||||||||||||
| Identification | |||||||||||||||||||||||||||||
| Name: | ethanesulfonate | ||||||||||||||||||||||||||||
| Description: | Ethanesulfonate is a member of the chemical class known as Depsipeptides. These are natural or synthetic compounds having sequences of amino and hydroxy carboxylic acid residues (usually -amino and -hydroxy acids), commonly but not necessarily regularly alternating. It is also called Coenzyme M. Coenzyme M is a coenzyme required for methyl-transfer reactions in the metabolism of methanogens. The coenzyme is an anion with the formula HSCH2CH2SO_3. It is named 2-mercaptoethanesulfonate and abbreviated HS | ||||||||||||||||||||||||||||
| Structure |
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| Synonyms: |
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| Chemical Formula: | C2H5O3S | ||||||||||||||||||||||||||||
| Average Molecular Weight: | 109.12 | ||||||||||||||||||||||||||||
| Monoisotopic Molecular Weight: | 108.996488775 | ||||||||||||||||||||||||||||
| InChI Key: | CCIVGXIOQKPBKL-UHFFFAOYSA-M | ||||||||||||||||||||||||||||
| InChI: | InChI=1S/C2H6O3S/c1-2-6(3,4)5/h2H2,1H3,(H,3,4,5)/p-1 | ||||||||||||||||||||||||||||
| CAS number: | Not Available | ||||||||||||||||||||||||||||
| IUPAC Name: | Not Available | ||||||||||||||||||||||||||||
| Traditional IUPAC Name: | Not Available | ||||||||||||||||||||||||||||
| SMILES: | CCS([O-])(=O)=O | ||||||||||||||||||||||||||||
| Chemical Taxonomy | |||||||||||||||||||||||||||||
| Taxonomy Description | Not Available | ||||||||||||||||||||||||||||
| Kingdom | Not Available | ||||||||||||||||||||||||||||
| Super Class | Not Available | ||||||||||||||||||||||||||||
| Class | Not Available | ||||||||||||||||||||||||||||
| Sub Class | Not Available | ||||||||||||||||||||||||||||
| Direct Parent | Not Available | ||||||||||||||||||||||||||||
| Alternative Parents | Not Available | ||||||||||||||||||||||||||||
| Substituents | Not Available | ||||||||||||||||||||||||||||
| Molecular Framework | Not Available | ||||||||||||||||||||||||||||
| External Descriptors | Not Available | ||||||||||||||||||||||||||||
| Physical Properties | |||||||||||||||||||||||||||||
| State: | Not Available | ||||||||||||||||||||||||||||
| Charge: | Not Available | ||||||||||||||||||||||||||||
| Melting point: | Not Available | ||||||||||||||||||||||||||||
| Experimental Properties: |
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| Predicted Properties | |||||||||||||||||||||||||||||
| Biological Properties | |||||||||||||||||||||||||||||
| Cellular Locations: | Cytoplasm | ||||||||||||||||||||||||||||
| Reactions: | ethanesulfonate + Oxygen + FMNH2 > Hydrogen ion + Water + Flavin Mononucleotide + Sulfite + Betaine aldehyde + Sulfite Adenosine triphosphate + Water + ethanesulfonate > Hydrogen ion + Phosphate + Adenosine diphosphate + ethanesulfonate + ADP Adenosine triphosphate + Water + ethanesulfonate > Hydrogen ion + Phosphate + Adenosine diphosphate + ethanesulfonate + ADP | ||||||||||||||||||||||||||||
| SMPDB Pathways: |
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| Biological Properties | |||||||||||||||||||||||||||||
| Cellular Locations: | Cytoplasm | ||||||||||||||||||||||||||||
| Reactions: | ethanesulfonate + Oxygen + FMNH2 > Hydrogen ion + Water + Flavin Mononucleotide + Sulfite + Betaine aldehyde + Sulfite Adenosine triphosphate + Water + ethanesulfonate > Hydrogen ion + Phosphate + Adenosine diphosphate + ethanesulfonate + ADP Adenosine triphosphate + Water + ethanesulfonate > Hydrogen ion + Phosphate + Adenosine diphosphate + ethanesulfonate + ADP | ||||||||||||||||||||||||||||
| Pathways: | Not Available | ||||||||||||||||||||||||||||
| Spectra | |||||||||||||||||||||||||||||
| Spectra: |
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| References | |||||||||||||||||||||||||||||
| References: | Not Available | ||||||||||||||||||||||||||||
| Synthesis Reference: | Not Available | ||||||||||||||||||||||||||||
| Material Safety Data Sheet (MSDS) | Not Available | ||||||||||||||||||||||||||||
| Links | |||||||||||||||||||||||||||||
| External Links: |
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Enzymes
- General function:
- Involved in alkanesulfonate monooxygenase activity
- Specific function:
- Involved in desulfonation of aliphatic sulfonates. Catalyzes the conversion of pentanesulfonic acid to sulfite and pentaldehyde and is able to desulfonate a wide range of sulfonated substrates including C-2 to C-10 unsubstituted linear alkanesulfonates, substituted ethanesulfonic acids and sulfonated buffers
- Gene Name:
- ssuD
- Locus Tag:
- PA3444
- Molecular weight:
- 41.6 kDa
Reactions
| An alkanesufonate (R-CH(2)-SO(3)H) + FMNH(2) + O(2) = an aldehyde (R-CHO) + FMN + sulfite + H(2)O. |
- General function:
- Involved in transporter activity
- Specific function:
- Part of a binding-protein-dependent transport system for aliphatic sulfonates. Probably responsible for the translocation of the substrate across the membrane
- Gene Name:
- ssuC
- Locus Tag:
- PA3443
- Molecular weight:
- 28.5 kDa
- General function:
- Involved in nucleotide binding
- Specific function:
- Part of the ABC transporter complex SsuABC involved in aliphatic sulfonates import. Responsible for energy coupling to the transport system (Probable)
- Gene Name:
- ssuB
- Locus Tag:
- PA3442
- Molecular weight:
- 29.8 kDa
Transporters
- General function:
- Involved in transporter activity
- Specific function:
- Part of a binding-protein-dependent transport system for aliphatic sulfonates. Probably responsible for the translocation of the substrate across the membrane
- Gene Name:
- ssuC
- Locus Tag:
- PA3443
- Molecular weight:
- 28.5 kDa
- General function:
- Involved in nucleotide binding
- Specific function:
- Part of the ABC transporter complex SsuABC involved in aliphatic sulfonates import. Responsible for energy coupling to the transport system (Probable)
- Gene Name:
- ssuB
- Locus Tag:
- PA3442
- Molecular weight:
- 29.8 kDa